I haven't looked at the temperatures but yesterday I experienced asynchronous video playback on a 1080p Netflix stream. Video was up to two seconds behind the audio but after a scene cut it was in sync again for 1 or 2 minutes. Maybe it has something to do with the cpu temperature.
I'm using the Pi4 without a case but I have a hifiberry on the GPIO
Quite certainly the CPU was maxed out and the RPi couldn't keep up with decoding the video.
While that can be caused by high temperature (and thus throttling, in which case you should see the thermometer icon pop up) I've also seen that with some streams (eg Black Mirror S01E02 at around 59:30-1:00:00) which have very high peak bitrate scenes.
The RPi4 probably needs to be overclocked to keep up with this - or switch to the next lower bitrate stream (IIRC the ~7Mbit/sec 1080p Black Mirror stream peaked to about 11-13Mbit/sec and ran into a/v sync issues, the ~6Mbit/sec 1080p stream played fine). Limiting the max bitrate may also help with that.
so long,
Hias