The adaptor has arrived and I've just done some initial testing as I haven't much time.
A 4K file that was buffering now plays fine. Copying a 110MB file across the network straight to the box took 3.1 secs which is about 35MB/s. A larger file started at about the same speed, dropped to zero, went back to the same speed etc. The inbuilt network port does the same, which I assume it due to the memory buffer being filled and the data been flushed to the slow writing USB stick I use for Libreelec.
Tried iperf to measure properly, but although this seems to connect no data seems to be transmitted. Need to try another of my machines.