The Armbian image I used is Armbian_20.02.1_Rock64_buster_current_5.4.20.
This boots fine. Using the commands, you provided, I copied u-boot image and then wrote it to the sdcard that contains your libreelec. DTB has been configured to load the rock64.dtb.
If everything is done correctly, the system must necessarily show the start LE (primary screen with the LE logo). Which DTB do you use ? Show the content (uEnv.txt). Show all the commands that you use to copy and write u-boot.