Firmware (not VL805 USB controller's firmware) is located on filesystem so in case of LE it depends on LE version. You can't change the firmware release with rpi-eeprom-update utility. To change the firmware version you need to replace the specific files (see https://github.com/raspberrypi/firmware ) on appropriate partition. You should avoid this as it's usually not necessary, rather install another LE version. I don't know which firmware version is on LE 10.0.1 as I am running LE 11 Nightlies (https://test.libreelec.tv/).
Bootloader on RPi 4B is located in EEPROM, also the bootloader configuration. I would not try to downgrade the bootloader version, at first compare the bootloader configs as recommended above (use vcgencmd bootloader_config command). The latest stable bootloader version is 2021-07-06 (see https://github.com/raspberrypi/rp…irmware/stable/) and I would recommend upgrading to latest. Also VL805 firmware should be 000138a1. See this post for detailed steps how to upgrade manually: RE: Is it possible already to set up a rpi4 with kernel 5.4?