HI , i'm not expert with pulseaudio framework but i think this could be possible,,,
1. HDMI output to TV configured as center speaker/channel.
2. Analog/Spdif onboard audio out as Front L/R channels virtually 2.1 depend on speakers setup
3. Bluetóoth A2DP Sink as Rear L/R channels
This will create 5.0/5.1 speaker configuration.
I don't know how to write config for pulseaudio and i don't know if this is be accepted by Libreelec subsystems and don't provide errors in menu/settings/audio.