If You connect to Your "LE Download folder" from Windows Explorer that should work without any hassle if You have the SMB sharing enabled.
( Sharing additional folders from LibreELEC via SMB [LibreELEC.wiki] )
Copy Your .zip's to "\\<IP adress>\Downloads" and paste .zip-files there (don't extract them!).
(no need to 'mount it, just connect using the address field)
You should now be able to find these files from Your LE file manager.