With 3D videos in MP4 it switches to full screen, that is good, but it switches the UI back to 2D again when stopping the video.
Thanks for testing. Two settings get closer to what you describe (Settings › Player › Videos, setting level "Advanced"):
- "Disable stereoscopic 3D mode when playback ended": switch it off and the UI stays in 3D after a video ends.
- "Playback mode of stereoscopic 3D videos": set it to "Preferred mode" so Kodi doesn't ask on every start.
3D for pictures doesn't exist in Kodi itself (LibreELEC ships Kodi unchanged here), so the place for that request is the Kodi forum's feature-request section or Kodi's GitHub.