Initial WireGuard support has been merged but I regard it as an experimental feature. It's merged to LE master branch, also to LE 9.2 branch as more people are likely to use it there and thus more issues will be discovered. I will need to bump connman and the wireguard module/tools packages before we release LE 9.2.1 (no schedule).
There is no wg-quick or wg0.conf due to the embedded packaging of LE - read Creating WireGuard Keys [LibreELEC.wiki] to understand how it's implemented.