Yes. IIRC Sync playback to display will break audio passthrough so just use Adjust display refresh rate. Kodi will then switch refreshrate and resolution (as configured in the whitelist) to match the video.
BTW: if you set up the whitelist better don't enable the 25/29.97/30Hz modes as that'll cause issues with interlaced content (kodi doesn't detect interlaced right and then tries to use eg 30Hz for 60Hz interlaced...)
so long,
Hias