There are 2 things mixed, the bootloader itself and the bootloader configuration.
I believe you already have the bootloader you need (although maybe not the latest available) installed.
The firmware version check / update can be easily done from Kodi - Settings - Libreelec - Updates - Firmware Updates
So you can easily upgrade the bootloader and VIA USB firmware to versions contained in your LE package which are quite fresh.
A manual upgrade way is described here: RE: Is it possible already to set up a rpi4 with kernel 5.4?
There's also outlined how to show the bootloader configuration. If you wish to edit it, you must be at least able to connect to your RPi through SSH client (Putty recommended) and use nano editor. Both Putty and nano are easy to use. Default username is root, password libreelec.
After connecting to your LE, copy and paste these commands:
cd /tmp
vcgencmd bootloader_config > bootconf.txt
nano bootconf.txt # edit the current bootloader configuration as you wish, then press CTRL+X, Y, ENTER to save file
rpi-eeprom-config /tmp/pieeprom.bin --config /tmp/bootconf.txt --out /tmp/pieeprom
rpi-eeprom-update -d -f /tmp/pieeprom
reboot