Thanks for the help.
I have uninstalled and reinstalled portainer first (before removing docker completely...).
The log is a bit different:
-- Journal begins at Sat 2022-01-29 16:26:30 WET, ends at Sat 2022-01-29 18:25:39 WET. --
Jan 29 16:26:41 LibreELEC systemd[1]: Started docker.linuxserver.portainer container.
Jan 29 16:26:42 LibreELEC sh[946]: Cannot connect to the Docker daemon at unix:///var/run/docker.sock. Is the docker daemon running?
Jan 29 16:26:42 LibreELEC sh[966]: docker: Cannot connect to the Docker daemon at unix:///var/run/docker.sock. Is the docker daemon running?.
Jan 29 16:26:42 LibreELEC sh[966]: See 'docker run --help'.
Jan 29 16:26:42 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Main process exited, code=exited, status=125/n/a
Jan 29 16:26:42 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Failed with result 'exit-code'.
Jan 29 16:26:52 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Scheduled restart job, restart counter is at 1.
Jan 29 16:26:52 LibreELEC systemd[1]: Stopped docker.linuxserver.portainer container.
Jan 29 16:26:52 LibreELEC systemd[1]: Started docker.linuxserver.portainer container.
Jan 29 16:27:09 LibreELEC sh[1306]: docker: Error response from daemon: network lsio not found.
Jan 29 16:27:09 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Main process exited, code=exited, status=125/n/a
Jan 29 16:27:09 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Failed with result 'exit-code'.
Jan 29 16:27:19 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Scheduled restart job, restart counter is at 2.
Jan 29 16:27:19 LibreELEC systemd[1]: Stopped docker.linuxserver.portainer container.
Jan 29 16:27:19 LibreELEC systemd[1]: Started docker.linuxserver.portainer container.
Jan 29 16:27:22 LibreELEC sh[1710]: docker: Error response from daemon: network lsio not found.
Jan 29 16:27:22 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Main process exited, code=exited, status=125/n/a
Jan 29 16:27:22 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Failed with result 'exit-code'.
Jan 29 16:27:32 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Scheduled restart job, restart counter is at 3.
Jan 29 16:27:32 LibreELEC systemd[1]: Stopped docker.linuxserver.portainer container.
Jan 29 16:27:32 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Start request repeated too quickly.
Jan 29 16:27:32 LibreELEC systemd[1]: docker.linuxserver.portainer.service: Failed with result 'exit-code'.
Jan 29 16:27:32 LibreELEC systemd[1]: Failed to start docker.linuxserver.portainer container.
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Would you still recommend scrubbing docker + portainer?
PS: I've tried another solution from the forum that has worked nicely for me. I've set up portainer directly:
docker run -d -p 8000:8000 -p 9000:9000 --name=portainer --restart=always -v /var/run/docker.sock:/var/run/docker.sock -v portainer_data:/data portainer/portainer-ce
Works fine after restarting kodi!