Tracks with DTS-MA & Dolby 5.1 are played correctly. I am still stunned.
Isn't DTS-MA high bitrate format? If so, Kodi transcodes it to something which is supported by HW.
Anyway, thanks for further testing. I'm a bit annoyed that GUI sounds doesn't work, but as you said, it might be your amp. I hope someone will provide feedback from testing this on some other amp. I don't think we can do anything more for now. Kernel patches will be submitted for inclusion in 5.17.