RPi5 boards will not boot from NVME devices without some additional configuration. If booted from LE on an SD card:
RPi5:~ # mount -o remount,rw /flash
RPi5:~ # nano /flash/config.txt
dtparam=pciex1 <= add to bottom of config.txt
dtparam=pciex1_gen=3 <= optional, enables faster speeds
Next you have to tell the EEPROM on the board to change the boot order:
RPi5:~ # rpi-eeprom-config --edit
BOOT_ORDER=0xf416 <= change the BOOT_ORDER line to this
PCIE_PROBE=1 <= might be needed with older HAT devices (try without first)
However, if the goal is to boot LE from the NVME drive, it needs to be configured with TWO partitions; one for boot files and one to be used as the persistent /storage area. If the drive is currently partitioned with a single partition and filesystem (containing some media) this is easiest done by copying media off the drive, booting LE from SD card, copying an LE image to /storage then writing it to the NVME drive using dd to effect a clean install; and then copying media back to the drive. Resizing and moving filesystems and partitions to avoid the need for moving media around can also be done, but it's not a trivial task to do from the console.
If you are fine booting LE from the SD card and simply want to use the device as extra storage that's no drama. Run pastekodi and mount | paste from the SSH console then share the URL(s) generated so we can check the drive mounted correctly and see where it mounted within the filesystem; the usual location is /var/media/<label> if the drive is named/labeled or /var/media/<UUID> if there is no name/label and the UUID is used instead.