Take a backup of the .kodi folder and contents from the RPiOS install, store it somewhere safe. Once you installed LE via PINN or NOOBS for some level of multi-boot support you can copy the backup file over and manually restore content by stopping Kodi, moving files to the right places, restarting Kodi again.
NB: It is not possible to install LE into a partition. It is not possible to use an NTFS drive as the /storage partition. You can use the NTFS drive as a separate media drive that's shared between several OS without issues, but /storage needs Unix filesystem permissions support.