2024-02-27 08:12:23.466 T:553 INFO <general>: Starting Kodi (19.5 (19.5.0) Git:19.5-Matrix). Platform: Linux ARM 32-bit
2024-02-27 08:12:23.466 T:553 INFO <general>: Using Release Kodi x32
2024-02-27 08:12:23.466 T:553 INFO <general>: Kodi compiled 2023-01-07 by GCC 10.2.0 for Linux ARM 32-bit version 5.10.110 (330350)
2024-02-27 08:12:23.466 T:553 INFO <general>: Running on BCM2835 with LibreELEC (official): 10.0.4, kernel: Linux ARM 32-bit version 5.10.110
2024-02-27 08:12:23.466 T:553 INFO <general>: FFmpeg version/source: 4.3.2-Kodi
The non-working file plays fine here, but RPi5 doesn't support H264 H/W decode and ffmpeg is software decoding the file. Please retest with a current LE12 nightly and run "pastekodi" and share the URL.