I am about to build another RPi5 system for a gift once the parts arrive. It will be in a Argon ONE v3 nvme case. I sure hope that is not going to have gremlins.
Sorry for that, but this wording in combination with that case I immediately remember: "... Don't get them wet. Do not feed (install) them after midnight. ..." 
WarpLover ,
I don't know if you want to use the Argon ONE V3 for LibreELEC or some other use case. But if you want to start directly with LE you should ensure manually that the settings, which you grabbed from the PVR thread, are there. Normally this will already happens if you follow the instructions from the manual. However, the steps described in the manual to run the scripts are intended for PiOS etc. and only partially work with LE.
To avoid sleepless nights I would start with a installation at SD card as first attempt, because the NVMe support is very sensitive regarding flexible pcb, NVMe model, bootloader version ...
Most buyers with NVMe issues seem to think it's just an issue with this case, but in my opinion external PCIe on RPi5 in general is a ride on a razor's edge with so many factors that can negatively affect it. The other concerns (reputation) regarding quality assurance/support are just an additional factor.
But: If you get a properly manufactured, I think the person that will get the gift will be very happy.
Regarding your original issue:
"Reboot" implies a reboot of the operating system, triggered by a normal shutdown, reset, power fail and so on. Your current situation looks like that only KODI was crashed and restarted after that. Indeed this looks like a reboot, because LibreELEC is very fast at startup. But it makes a huge difference for troubleshooting.
You can simple check that after such event, if you connect to the console via SSH and use 'uptime' to see how long the operating system is up.
I know that KODI with the current versions of LE12/13 crashes if the played video stream has some defective frames and additional software deinterlacing is on. If the hardware acceleration for deinterlacing is in use, there is a pixelation at this points, but KODI doesn't crash.
Because you reported the issue with 2 systems, maybe you triggers the issue with the content you play or a installed add-on/skin.