Hi arhodiewithsoul,
It looks like your hard drives are formatted as NTFS and are being marked as "dirty" by the system (meaning the system has decided they are having issues and flipped a flag to have them checked).
NTFS is a Windows format and LibreELEC dose not have the needed utilities to check and repair any problems on these drives.
From your Logs:
Jun 18 18:48:19.535178 MaximusPi systemd[1]: Starting [email protected]...
Jun 18 18:48:19.567347 MaximusPi kernel: ext3: Unknown parameter 'fmask'
Jun 18 18:48:19.567525 MaximusPi kernel: ext2: Unknown parameter 'fmask'
Jun 18 18:48:19.567613 MaximusPi kernel: ext4: Unknown parameter 'fmask'
Jun 18 18:48:19.567675 MaximusPi kernel: squashfs: Unknown parameter 'fmask'
Jun 18 18:48:19.567733 MaximusPi kernel: hfsplus: unable to parse mount options
Jun 18 18:48:19.567797 MaximusPi kernel: hfs: unable to parse mount options
Jun 18 18:48:19.567854 MaximusPi kernel: UDF-fs: bad mount option "fmask=0133" or missing value
Jun 18 18:48:19.570678 MaximusPi kernel: F2FS-fs (sda1): Magic Mismatch, valid(0xf2f52010) - read(0xc0856600)
Jun 18 18:48:19.570812 MaximusPi kernel: F2FS-fs (sda1): Can't find valid F2FS filesystem in 1th superblock
Jun 18 18:48:19.570873 MaximusPi kernel: F2FS-fs (sda1): Magic Mismatch, valid(0xf2f52010) - read(0x0)
Jun 18 18:48:19.570928 MaximusPi kernel: F2FS-fs (sda1): Can't find valid F2FS filesystem in 2th superblock
Jun 18 18:48:19.570982 MaximusPi kernel: fuseblk: Unknown parameter 'fmask'
Jun 18 18:48:19.620671 MaximusPi kernel: ntfs3: sda1: volume is dirty and "force" flag is not set!
Jun 18 18:48:19.620906 MaximusPi udevil[7193]: mount: mounting /dev/sda1 on /media/Persephone failed: Invalid argument
Jun 18 18:48:19.621825 MaximusPi udevil[7189]: mount: mounting /dev/sda1 on /media/Persephone failed: No such device
Jun 18 18:48:19.692860 MaximusPi systemd[1]: Finished [email protected].
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When you run the check/repair on the drives in windows, it flips the flag on the drive saying all is well now.
Unfortunately this problem may continue to happen with your current setup.
Reformatting the drive will delete ALL DATA on the drive, so you must back it up first (I understand that is not always do-able). You may have to look at serving the data from a different system (windows or a linux distribution that handles NTFS).