Thank you for your fast responses.
After SSH login as root I find myself in the /storage directory with the prompt
LibreELEC (official): 10.95.0 (RPi2.arm)
<device>:~ #
As I was not aware of being already in in the /storage directory I wrongly followed the first step of the wiki which instructs to:
QuoteConnect to your LibreELEC HTPC with SSH.
mkdir /storage/recordings
So I erroneously created a /storage/storage/recordings directory.
For me an instruction like:
~ # mkdir /recordings
and in step 2 accordingly:
~ # nano /.config/system.d/storage-recordings.mount
or the gedakc hint:
QuoteNormally the root user has a home directory of / but on LibreELEC the root user has a home directory of /storage
would have been more helpful.
It also would have saved me and you some time, if I found the reason for my misunderstanding by myself and if I had studied other parts of the the well written and inviting wiki more thoroughly before configuring the network share and writing this comment.