Thanks for the log!
There's currently a bug playing VP8 videos, better avoid these files for now, they lead to kernel/firmware issues and you need to reboot the RPi to get it back into a proper working state. I've informed the RPi devs and hope we'll get a fix soon.
Concerning the H264 issue: could you please test with this build: LibreELEC-RPi4.arm-10.0-devel-20210901104638-c91d4d4.tar ?
This is our current libreelec-10.0 development version and it includes several fixes for video player crashes. The "V207 TS - AVC 1080p 24fps 8bit - AAC2.0.ts" file played fine with it here (tried starting it a couple of times).
so long,
Hias