You have to be careful, there are two separate cases for IR, only one defaults to RC6 MCE remote:
1. Board is suspended or in sleep mode. Power management firmware is in charge of IR. If board comes with IR remote (TV boxes only), power key on that IR remote wakes up board. If IR remote is not bundled with the board (all SBCs), then RC6 MCE power key is default (your case).
2. Board is running, e.g. Kodi. In this case, Linux is in charge of IR. Again, if board comes with IR remote, correct keymap should be already active. If not, there is no default, you have to set it up (your case).