I did notice something I haven’t seen. When trying to play the John Adams HBO Mini Series MKV rips and even some of the Enterprise episodes I have tested with in the past it causes LibreElec to reboot and go back to the load screen. Never seen that before. Once it boots back up I click on them again and they play as normal. What could be causing this?
If your current advancedsettings.xml solves the original issue, disable (comment out) force_turbo=1 at config.txt.
If the reboot issue persists after this, open a new thread and provide a log file (pastekodi link) with debugging enabled on GUI.